DETERMINATION OF VISCOSITY-AVERAGE MOLECULAR WEIGHT USING INTRINSIC VISCOSITY MEASUREMENT
DOI:
https://doi.org/10.65405/s78twf11Keywords:
Ostwald Viscometer, viscosity average molecular weight, intrinsic viscosity, polymerAbstract
In the present work, two types of polymers are polystyrene (PS) and polydimethylsiloxane (PDMS) were used, where Molecular weight of polymers can be determined by different techniques such as intrinsic viscosity measurement. Determination of molecular weight by intrinsic viscosity measurement is a simple method for characterization of polymers. Different concentrations of polymers were prepared and measurement was done at room temperature. The flow time data was used to calculate the intrinsic viscosity by extrapolating the reduced viscosity to zero concentration. The value of intrinsic viscosity was then recalculated into the viscosity-average molecular weight using Mark-Houwink equation. The results were obtained to calculate the viscosity average molecular weight of both types of polymers respectively, PS is (97,223.05) and PDMS is (100,359.98) and are considered good results.
Downloads
References
[1] Goddard, E. D., Ananthapadmanabhan, K. (1993), Interactions of Surfactants with Polymers and Proteins; CRC Press, Boca Raton.
[2] Narain, R. (2020). Polymer Science and Nanotechnology: Fundamentals and Applications. 1st ed. Elsevier.
[3] Toms, B.A., Some Observations on The Flow of Linear Polymer Solutions through Straight Tubes at Large Reynolds numbers, Proc. 1st Intern. Congr. Rheol. , Vol.2, pp 135-141, North Holland, (1948).
[4] Truong, V. T. (2002), Drag Reduction Technologies. http://www.dsto.defence.gov. au/corporate/reports/DSTO-GD-0290.pdf.
[5] Barth, H. G. , Mays. J. W. (1991), Modern Methods of Polymer Characterization.1st ed., New York: Wiley, PP. 2321.
[6] Brandrup, J. Immergut, E. H. and Grulke, E. A. (1999), Polymer Handbook. 4th ed. New York: Wiley.
[7] Taylor and Francis Group (2006), Introduction to Polymer Science and Chemistry. Boca Raton New York.
[8] Brown, R. P. (1981), Handbook of Plastics Test Methods. 2nd edition, George Godwin Ltd: London.
[9] Appletion, J. D. Hooker, P. J. and Smith, N. J. P. (1995), Report on the abatement of volatile organic compounds from stationary sources. Report to the department of the environment, London. contract no. PECD 7/12/138.
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Comprehensive Journal of Science

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.








